Fire is ionised air. An ion is an atom that has had electrons taken away from it. When gas gets hot, the atoms move around very fast, and when they collide, the collisions have enough energy to knock electrons out of the atom. When the electrons join with another atom, they produce light (in fact, this is what light is – electrons emitting energy as they jump up and down energy levels around an atom). The frequency of light is related to its energy, so as the gas gets hotter, the flame has a higher frequency of light. Blue has a higher frequency than red, which is why hotter flames are blue and cooler flames are red. Wood burns because the chemical energy in the plants is released when it gets hot, creating more heat and causing the fire to grow.
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